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Paul Dervan, Fawaz Aldabbagh, Per B. Zetterlund and Bunichiro Yamada Mechanism and kinetics of the imidazolidinone nitroxide-mediated free-radical polymerization of styrene Journal of Polymer Science Part A: Polymer Chemistry 41

Article first published online: 9 DEC 2002 | DOI: 10.1002/pola.10582

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We report the first polymerization of styrene initiated by low molecular weight polymeric alkoxyamines of imidazolidinone nitroxides. Experimentally obtained rate constants and equilibrium constants are used to interpret the mechanism of the polymerization process.

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