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Alexandra I. Costa, Luís F. V. Ferreira and José V. Prata Novel fluorescent (p-phenylene ethynylene)-calix[4]arene-based polymer: Design, synthesis, and properties Journal of Polymer Science Part A: Polymer Chemistry 46

Article first published online: 26 AUG 2008 | DOI: 10.1002/pola.22957

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Pd/Cu-catalyzed cross-coupling polymerization of a lower rim single-bridged bis-calix[4]arene with 1,4-diethynylbenzene was successfully accomplished leading to a novel fluorescent (p-phenylene ethynylene)-calix[4]arene-based polymer (CALIX-PPE) in excellent yield.

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