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Jinsheng Song, Chi Zhang, Cuihong Li, Weiwei Li, Ruiping Qin, Binsong Li, Zhengping Liu and Zhishan Bo Conjugated polymers with broad absorption: Synthesis and application in polymer solar cells Journal of Polymer Science Part A: Polymer Chemistry 48

Version of Record online: 13 MAY 2010 | DOI: 10.1002/pola.24035

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A series of main chain donor-acceptor low-bandgap conjugated polymers were designed, synthesized; the polymers in films exhibited broad absorption ranging from 300 to 1000 nm with optical bandgaps of around 1.40 eV. Photovoltaic devices based on polymer/PC61BM blends were fabricated by spin-coating from dichlorobenzene. With 1,8-diiodooctane as an additive, device based on polymer P1 shows the best PCE of 2.44%.

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