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Lee R. Cambrea, Matthew C. Davis, Thomas J. Groshens, Andrew J. Guenthner, Kevin R. Lamison and Joseph M. Mabry A new room-temperature liquid, high-performance tricyanate ester Journal of Polymer Science Part A: Polymer Chemistry 48

Article first published online: 2 SEP 2010 | DOI: 10.1002/pola.24246

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The design, synthesis, and characterization of a new tricyanate ester that is liquid at room temperature is presented. Thermal analysis of cyclotrimerization showed that the monomer could be cured to >96% at a temperature of only 210 °C. The resulting polycyanurate had a Tg of 305 °C. Hot water degradation tests of the polycyanurate showed that the resin's decrease in performance, “wet” Tg of 255 °C, was considerably less than that found with a commercial dicyanate ester.

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