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Swapna Krishnamoorthy, Mehul Haria, Blythe E. Fortier-mcgill, M. A. Jafar Mazumder, Erica I. Robinson, Yan Xia, Nicholas A. D. Burke and Harald D. H. Stöver High Tg microspheres by dispersion copolymerization of N-phenylmaleimide with styrenic or alkyl vinyl ether monomers Journal of Polymer Science Part A: Polymer Chemistry 49

Article first published online: 3 NOV 2010 | DOI: 10.1002/pola.24440

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Polymer microspheres with high Tg values (165–225 °C) were prepared by dispersion copolymerization of N-phenylmaleimide with styrenic or alkyl vinyl ether comonomers, where the Tg value of the particles could be adjusted through the selection of the appropriate comonomer(s). The image shows the effect of polymerization solvent (ethanol with varying amounts of methyl ethyl ketone) on the size and morphology of styrene-phenylmaleimide particles made by dispersion polymerization.

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