Shi Wu, Nianfa Yang, Yanling Liu, Jing Cao, Hai Hu, Yunkai Sun and Ji Liu Optically active helical polymer from radical polymerization of menthyl vinyl ketone Journal of Polymer Science Part A: Polymer Chemistry 49
Menthyl vinyl ketone (MVK) was radically polymerized to obtain poly-MVK with excess of one-handed helical sense. The radically polymerized poly-MVK kept stable one-handed helical conformation in solution. The optical rotation and the CD intensity of the radically polymerized poly-MVK were larger than that of the anionically polymerized poly-MVK. The molecular weight of the radically polymerized poly-MVK was much larger than that of the THF-soluble part of the anionically polymerized poly-MVK.
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