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Yuping Yuan, Tsuyoshi Michinobu, Minoru Ashizawa and Takehiko Mori Microwave-assisted TCNE/TCNQ addition to poly(thienyleneethynylene) derivative for construction of donor–acceptor chromophores Journal of Polymer Science Part A: Polymer Chemistry 49

Article first published online: 3 JAN 2011 | DOI: 10.1002/pola.24515

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Small cyano-containing acceptor molecules, such as tetracyanoethylene and tetracyanoquinodimethane, underwent the addition reaction with the alkyne moieties of the poly(thienyleneethynylene) derivative under microwave irradiation, which produced donor–acceptor-type polymers with enhanced I2-doped conductivities.

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