Padraig O'connor, Per B. Zetterlund and Fawaz Aldabbagh Nitroxide-mediated stabilizer-free inverse suspension polymerization of N-isopropylacrylamide in supercritical carbon dioxide Journal of Polymer Science Part A: Polymer Chemistry 49
The first inverse dispersed phase controlled/living polymerization in supercritical carbon dioxide (scCO2) is described. The nitroxide-mediated radical polymerization of N-isopropylacrylamide proceeded in the absence of stabilizer to high conversion giving a dry powder. The polymerization and purification does not require the use of environmentally damaging volatile organic compound.
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