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Ivan Gitsov, Arsen Simonyan, Lili Wang, Albert Krastanov, Stuart W. Tanenbaum and Dave Kiemle Polymer-assisted biocatalysis: Unprecedented enzymatic oxidation of fullerene in aqueous medium Journal of Polymer Science Part A: Polymer Chemistry 50

Article first published online: 23 SEP 2011 | DOI: 10.1002/pola.24995

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For the first time fullerene can be oxidized in water and under environmentally friendly reaction conditions by new biocatalysts, constructed from laccase and linear-dendritic copolymers. The oxidation products are formed in 50-78 % yield and the copolymer-enzymatic complex can be recycled by simple filtration and reused.

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