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Weizhong Yuan, Jinchun Zhang, Hui Zou and Jie Ren Synthesis, crystalline morphologies, self-assembly, and properties of H-shaped amphiphilic dually responsive terpolymers Journal of Polymer Science Part A: Polymer Chemistry 50

Article first published online: 23 MAR 2012 | DOI: 10.1002/pola.26032

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Amphiphilic H-shaped terpolymers PLLA-b-(PDMAEMA-b-)PCL(-b-PDMAEMA)-b-PLLA&!rpar; were synthesized by the combination of ROP, ATRP and click chemistry. The amphiphilic terpolymers can self-assemble into spherical nano-micelles in water. The dually responsive properties of temperature and pH can be observed through DLS investigation. Moreover, the H-shaped terpolymer shows the unique thermal properties and crystalline morphologies according to DSC and POM measurements.

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