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Wen Li, Xiuqiang Zhang, Jue Wang, Xiao Qiao, Kun Liu and Afang Zhang Peptidic molecular brushes with enhanced chirality Journal of Polymer Science Part A: Polymer Chemistry 50

Version of Record online: 21 JUN 2012 | DOI: 10.1002/pola.26208

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Brush-like polymers with monodispersed oligolysine side chains were efficiently synthesized and their secondary structures were analyzed. This molecular brush architecture affords the short peptide side chains a constrained environment to adopt enhanced chirality in solutions at various temperatures because of the reinforced interactions between the proximately packed peptide chains.

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