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David Rayeroux, Vincent Lapinte and Patrick Lacroix-Desmazes One-pot synthesis of amphiphilic diblock copolymers of poly(styrene) and poly(2-methyl-2-oxazoline) by the direct combination of reverse iodine transfer polymerization (RITP) and cationic ring-opening polymerization (CROP) processes Journal of Polymer Science Part A: Polymer Chemistry 50

Version of Record online: 17 AUG 2012 | DOI: 10.1002/pola.26291

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A iodo-terminated polystyrene (PS-I) synthesized by reverse iodine transfer polymerization (RITP) was directly used as macroinitiator in the cationic ring-opening polymerization of 2-methyl-2-oxazoline to afford a water-soluble diblock copolymer. This is the first example of combination of RITP and CROP in macromolecular engineering.

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