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Andreas Mautner, Xiaohua Qin, Harald Wutzel, Samuel C. Ligon, Barbara Kapeller, Doris Moser, Guenter Russmueller, Juergen Stampfl and Robert Liska Thiol-ene photopolymerization for efficient curing of vinyl esters Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 21 SEP 2012 | DOI: 10.1002/pola.26365

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Vinyl esters exhibit low toxicity together with good mechanical properties, which qualifies them to be potential alternatives to state-of-the-art methacrylates. A drawback of a certain class of these vinyl esters containing easily abstractable hydrogens is their moderate reactivity. With the help of thiolene polymerization, the reactivity was enormously improved up to a level of acrylates.

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