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Christopher M. Bates, Marco A. Bedolla Pantoja, Jeffrey R. Strahan, Leon M. Dean, Brennen K. Mueller, Christopher J. Ellison, Paul F. Nealey and C. Grant Willson Synthesis and thin-film orientation of poly(styrene-block-trimethylsilylisoprene) Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 12 OCT 2012 | DOI: 10.1002/pola.26375

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The synthesis of a diblock copolymer is described, which undergoes spontaneous assembly into cylindrical patterns. The matrix surrounding the cylinders can be selectively etched away to leave structures with dimensions on the nanoscale. The orientation and ordering of these structures is demonstrated. Structures of this sort are valuable for use in nano-manufacturing of devices such as microelectronics and hard disk drives.

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