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Yasuhiro Morisaki, Shizue Ueno and Yoshiki Chujo [2.2]paracyclophane-based through-space conjugated polymers with fluorescence quenchers Journal of Polymer Science Part A: Polymer Chemistry 51

Article first published online: 9 OCT 2012 | DOI: 10.1002/pola.26382

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[2.2]Paracyclophane-based through-space conjugated polymers were prepared, in which π-electron systems, i.e., poly(p-arylene-ethynylene) units, are partially π-stacked and layered one-dimensionally. In the polymers, fluorescence quenchers, such as anthraquinone and ferrocene, exist at the polymer termini. Fluorescence emission from the stacked π-electron systems is effectively quenched by the terminal π-electron systems through the polymer chain.

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