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Weifeng Liu, Kailun Zhang, Hong Fan, Wen-Jun Wang, Bo-Geng Li and Shiping Zhu Living copolymerization of ethylene/1-octene with fluorinated FI-Ti catalyst Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 23 OCT 2012 | DOI: 10.1002/pola.26398

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The living copolymerization kinetics of ethylene with 1-octene was studied with the fluorinated FI-Ti catalyst system. The livingness behavior was retained at an extremely high comonomer feeding ratio of 0.953. The comonomer incorporation reached up to 32.7 mol %. The copolymer composition drifting was minor. The reactivity ratios were determined and it was found that heterogeneity had a significant effect on the copolymerization kinetics. The reactivity ratios were independent of temperature in the range of 0–35°C.

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