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Jie Song, Eunji Lee and Byoung-Ki Cho Clicked (AB)2C-type miktoarm terpolymers: Synthesis, thermal and self-assembly properties, and preparation of nanoporous materials Journal of Polymer Science Part A: Polymer Chemistry 51

Article first published online: 29 OCT 2012 | DOI: 10.1002/pola.26403

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A (PEO-PS)2-PLA terpolymer self-assembles into a two-phase columnar structure consisting of poly(ethylene oxide) (PEO)/polylactide (PLA) cylindrical domains in a rigid polystyrene (PS) matrix. In contrast, the ion doping of the PEO block induces a three-phase lamellar morphology. Meanwhile, by eliminating the confined PLA block in the columnar morphology, a nanoporous material with hydrophilic PEO walls can be produced.

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