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Ingmar Polenz, Friedrich Georg Schmidt and Stefan Spange Acceleration of the imine base/isocyanate (IBI)-mediated polymerization of MMA caused by ionic liquid traces Journal of Polymer Science Part A: Polymer Chemistry 51

Article first published online: 6 NOV 2012 | DOI: 10.1002/pola.26422

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Traces of ionic liquids (ILs) accelerate the novel imine base/isocyanate (IBI)-mediated radical polymerization of methyl methacrylate (MMA). Both the brutto polymerization rate constant kBr,0 and the activation temperature of IBI mixtures are influenced. Herein, results are reported on the polymerization kinetics of several IBI combinations in the presence of selected ILs whereas a comparison with non-IL containing initiator mixtures is given. The interaction strength of the IL with each IBI component and MMA was determined by means of ATR FT MIR spectroscopy.

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