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Sergei V. Kostjuk, Hui Yee Yeong and Brigitte Voit Cationic polymerization of isobutylene at room temperature Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 6 NOV 2012 | DOI: 10.1002/pola.26423

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Highly reactive polyisobutylene (HR PIB) can be successfully prepared by cationic polymerizaion at room temperature using special initiating and catalyst systems like modified Lewis acids and metal complexes associated with weakly coordinating anions. Successful systems allow chain transfer to be regulated and protic activity to be reduced.

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