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Qiang Huang, Yixian Wu and Jie Dan Cationic polymerization of isobutyl vinyl ether coinitiated with heteropolyacid or its salts in aqueous medium Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 8 NOV 2012 | DOI: 10.1002/pola.26431

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Suspension cationic polymerization of IBVE coinitiated by AlPW12O40 in aqueous medium could be achieved to synthesize poly(IBVE) with m diad of around 60% in the presence of a sufficient amount of HCl. The cationic polymerization of IBVE in aqueous medium in the presence of HCl proceeded extremely rapidly even at very low concentration of AlPW12O40. All the poly(IBVE) growing chains were terminated by H2O and further transferred to aldehyde and alkenal terminal groups.

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