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Johannes Arend van Hensbergen, Robert P. Burford and Andrew B. Lowe Post-functionalization of a ROMP polymer backbone via radical thiol-ene coupling chemistry Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 8 NOV 2012 | DOI: 10.1002/pola.26433

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The radical thiol-ene reaction is used to modify the backbone of a common ROMP-prepared homopolymer. Hydrothiolation is successful in most instances in facilitating the ready introduction of a range of functionality including OH, pyrrole, alkyl, ester, and POSS species while still retaining the well-defined characteristics of the parent polymer.

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