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Guang-Peng Wu, Peng-Xiang Xu, Yu-Ping Zu, Wei-Min Ren and Xiao-Bing Lu Cobalt(III)-complex-mediated terpolymerization of CO2, styrene oxide, and epoxides with an electron-donating group Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 19 NOV 2012 | DOI: 10.1002/pola.26444

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The terpolymerization of CO2, styrene oxide and epoxide, bearing an electron-donating group has been achieved with the use of cobalt-based complexes as catalyst at mild conditions. A random distribution of the two kinds of carbonate units is present in the CO2/styrene oxide/propylene oxide terpolymer, whereas an alternating nature of the two different carbonate units predominantly exists in the CO2/styrene oxide/CHO terpolymer.

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