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Takahiro Miyata, Kozo Matsumoto, Takeshi Endo, Shigeaki Yonemori and Shoji Watanabe Synthesis and radical polymerization of styrene-based monomer having a five-membered cyclic dithiocarbonate structure Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 24 DEC 2012 | DOI: 10.1002/pola.26508

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A styrene-based monomer having a five-membered cyclic dithiocarbonate structure 4-vinylbenzyl 1,3-oxathiolane-2-thione-5-ylmethyl ether (VBTE) was prepared by addition of carbon disulfide to 4-vinylbenzyl glycidyl ether. Polymerization of the VBTE readily proceeded using 2,2′-azobisisobutyronitrile as an initiator to give polyVBTE.

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