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Yun-Hai Yu, Xiao-Hui Liu, Di Jia, Bo-Wen Cheng, Fei-Jun Zhang, Hui-Na Li, Peng Chen and Shan Xie “Nascent” Cu(0) nanoparticles-mediated single electron transfer living radical polymerization of acrylonitrile at ambient temperature Journal of Polymer Science Part A: Polymer Chemistry 51

Article first published online: 8 JAN 2013 | DOI: 10.1002/pola.26519

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Zn(0)/CuBr2 (where CuBr2 concentrations are in the range of 10–50 ppm) was firstly used to catalyze radical polymerization of acrylonitrile at ambient temperature. The polymerization displayed typical living radical polymerization characteristics, as evidenced by pseudo first-order kinetics of polymerization, linear increase of number-average molecular weight, and low polydispersity index value.

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