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Sudip K. De and Manish Bhattacharjee Titanium(IV) nonmetallocene complex catalyzed aqueous homopolymerization and copolymerization of styrene and methyl methacrylate: An Environmentally friendly approach to ultrahigh molecular weight polymer nanoparticles Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 5 JAN 2013 | DOI: 10.1002/pola.26520

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A new titanium complex bearing an asymmetric ligand has been synthesized and characterized. This complex has been found to catalyze aqueous homopolymerization and copolymerization of MMA and styrene at room temperature to afford polymer nanoparticles. The polymers obtained are of very high molecular weights.

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