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Wei Wu, Haibo Xu, Dezhi Shen, Tian Qiu and Li-Juan Fan One-step synthesis of a thienylenepyridazinylenethienylene-based coil-rod-coil copolymer with enhanced emission and improved fluorescence stability Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 9 JAN 2013 | DOI: 10.1002/pola.26535

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A coil-rod-coil copolymer (PEG-OEPETPT-PEG) has been synthesized in one-step via Sonogashira coupling polymerization using two bifunctional small molecular mononers to form the conjugated block and one monofunctional macromolecular monomer as the coil block. The introduction of the coil onto the conjugated block retards the aggregation induced by water and therefore enhances the emission and improves the fluorescence stability of PEG-OEPETPT-PEG compared to the conjugated polymer counterpart without the coils.

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