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Motohisa Azechi, Kozo Matsumoto and Takeshi Endo Anionic ring-opening polymerization of a five-membered cyclic carbonate having a glucopyranoside structure Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 9 JAN 2013 | DOI: 10.1002/pola.26538

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The effect of polymerization conditions on anionic ring-opening polymerization behaviors of the five-membered cyclic carbonate, MBCG, is investigated. The corresponding polymers are obtained in high yield by using stronger nucleophilic initiators such as n-butyllithium, lithium tert-butoxide, sodium tert-butoxide, potassium tert-butoxide, and 1,8-diazabicyclo[5.4.0]undec-7-ene.

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