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Yiyu Zhan, Zhengbiao Zhang, Xiangqiang Pan, Jian Zhu, Nianchen Zhou and Xiulin Zhu A cyclic selenium-based reversible addition-fragmentation chain transfer agent mediated polymerization of vinyl acetate Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 17 JAN 2013 | DOI: 10.1002/pola.26539

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A cyclic selenium-based RAFT agent, RAFT-Se, was utilized in the RAFT polymerizations of VAc. RAFT-Se showed better control over molecular weights than its analog, RAFT-S. One or more RAFT-Se was incorporated into the resultant poly(VAc) main chain due to the cyclic structure. Considering the biofunction of PVAc-related polymer and the Se-containing material, this work undoubtedly presents a good junction of both.

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