Yichao Lin, Jun Zheng, Feng Liu and Tao Tang Synthesis of well-defined comb-like graft (co)polymers by nucleophilic substitution reaction between living polymers and polyhalohydrocarbon Journal of Polymer Science Part A: Polymer Chemistry 51
A modular synthesis approach with living anionic polymerization is presented for the preparation of well-defined graft (co)polymers. Hydrozirconation of 1,2-polybutadiene and halogenolysis is achieved for controlled synthesis of the reactive backbone, which was coupled with living polymers for well-defined graft polymers. Both the backbone and the side chain are nicely designed by living anionic polymerization, for series graft polymers with tunable size, chemical composition, and grafting density.
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