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Aurica Farcas, Silvia Janietz, Valeria Harabagiu, Philippe Guegan and Pierre-Henri Aubert Synthesis and electro-optical properties of polyfluorene modified with randomly distributed electron-donor and rotaxane electron-acceptor structural units in the main chain Journal of Polymer Science Part A: Polymer Chemistry 51

Article first published online: 24 JAN 2013 | DOI: 10.1002/pola.26546

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Host-guest complexation of 9-dicyanomethylenefluorene (an electron-accepting molecule) into γCD cavities leads to the improvement of the fluorescence efficiency by protection from solvent quenching (decreasing nonradiative decay pathways), and hinders the aggregation tendency with beneficial effects on morphological and adhesion properties.

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