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Ching Hsuan Lin, Sheng Lung Chang, Yu Ru Wang, Chin Kuang Hsu and Tzong Yuan Juang Synthesis of thermosetting polyetherimide-containing allyl groups Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 28 JAN 2013 | DOI: 10.1002/pola.26549

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An organosoluble polyetherimide (PEI) (4) containing an allyl group was successfully prepared. PEI (5), obtained from the thermal curing of PEI (4) at 300 °C, displays a much higher Tg value (307 °C) and a lower coefficient of thermal expansion (29 ppm/°C) than the PEI (4) (Tg 253 °C, CTE 52 ppm/°C).

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