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Joonkeun Min, Hee-Soo Yoo, Priyank N. Shah, Chang-Geun Chae and Jae-Suk Lee Enolate anionic initiator, sodium deoxybenzoin, for leading living natures by formation of aggregators at the growth chain ends Journal of Polymer Science Part A: Polymer Chemistry 51

Article first published online: 30 JAN 2013 | DOI: 10.1002/pola.26550

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Self-aggregated sodium deoxybenzoin (Na-DB) molecules can form a trimeric aggregator in tetrahydrofuran and vacuum state. Upon addition of hexyisocyanate, a single molecule of Na-DB initiates the monomers and two other molecules to form a complex with a growing amidate anion of polyisocyanate. Thus, Na-DB can perform dual functions: initiation and additive effects.

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