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Stefanie A. Sydlik, Paula A. Delgado, Sotaro Inomata, Brett VanVeller, Yong Yang, Timothy M. Swager and Kenneth B. Wagener Triptycene-containing polyetherolefins via acyclic diene metathesis polymerization Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 30 JAN 2013 | DOI: 10.1002/pola.26557

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Several new triptycene-containing polyetherolefins were synthesized via acyclic diene metathesis polymerization. Inclusion of triptycene was found to increase the glass transition temperature over 100 °C from the control polymer without any triptycene. Varying the amounts and orientations of triptycene was found to increase the stiffness, toughness, and ductility of the polymer at room temperature.

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