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Kie Yong Cho, Seung Sang Hwang, Ho Gyu Yoon and Kyung-Youl Baek Electroactive methacrylate-based triblock copolymer elastomer for actuator application Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 19 FEB 2013 | DOI: 10.1002/pola.26563

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A series of well-defined MMA-DMA-MMA triblock copolymers with different molecular weights and compositions were synthesized by in situ sequential block copolymerization of DMA followed by MMA from a difunctional initiator through Ru-based living radical polymerization. Obtained triblock copolymers showed periodically well-organized morphologies both in bulk and in film states, giving excellent actuation performances at relatively lower electric fields due to their polar methacrylate groups (k), lower modulus, and microstructures.

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