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Prodip Sarker, Saif U. R. Rehman and Stephen Rimmer A macromonomer approach to the synthesis of poly(1,1-bis(ethoxycarbonyl)-2-vinyl cyclopropane-graft-dimethyl siloxane) Journal of Polymer Science Part A: Polymer Chemistry 51

Article first published online: 7 FEB 2013 | DOI: 10.1002/pola.26565

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The first graft copolymers with poly(vinyl cyclopropane) backbones were produced by first preparing a poly(dimethyl siloxane) with an allyl carbonate at one end group. This was then polymerized with 1,1-bis(ethoxycarbonyl)-2-vinyl cyclopropane (ECVP). The materials have low glass transition temperatures that were dependent on polymer composition.

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