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Ganwei Zhang, Jiwen Hu, Guping He, Hailiang Zou, Feng Liu, Chengmin Hou, Hongsheng Luo and Yuanyuan Tu Statistical fluorinated copolymers from heterogeneous atom transfer radical copolymerization of styrene and 2,2,2-trifluoroethyl methacrylate with similar reactivity ratios Journal of Polymer Science Part A: Polymer Chemistry 51

Article first published online: 7 FEB 2013 | DOI: 10.1002/pola.26568

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Reported here is a novel synthetic strategy for preparing gradient fluorinated copolymers with statistical structure of azeotropic or gradient composition from styrene (S) and 2,2,2-trifluoroethyl methacrylate (T) with very similar reactivity ratios via heterogeneous ATRP.

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