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Ying Liang, Delong Liu and Hou Chen Poly(methyl methacrylate-co-pentaerythritol tetraacrylate-co-butyl methacrylate)-g-polystyrene: Synthesis and high oil-absorption property Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 6 FEB 2013 | DOI: 10.1002/pola.26576

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High oil-absorption resin was successfully prepared via living radical polymerization on the surface of a polystyrene resin-supported N-chlorosulfonamide group utilizing MMA and BMA as monomers, FeCl3/IDA as the catalyst system, PETEA as a cross-linker, and VC as a reducing agent. The polymerization proceeded in a “living” manner as indicated by the linearity of the kinetic plot. The oil-absorption resin shows a toluene absorption capacity of 21 g g−1. The adsorption of oil behaves as a pseudo-first-orderkinetic model rather than a pseudo-second-order kinetic model.

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