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CaiFei Wang, ChunHua Zhao, JiaQin Sun, SanQing Huang, XiangDong Liu and Takeshi Endo Synthesis and thermal properties of a bio-based polybenzoxazine with curing promoter Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 19 FEB 2013 | DOI: 10.1002/pola.26587

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A fully bio-based benzoxazine monomer has been synthesized from guaiacol, furfurylamine, and paraformaldehyde. Its polymerization behaviors, including the ring-opening polymerization temperature, the gel point time, and the char yield of the cured resin, were significantly improved by using methyl p-toluenesulfonate as promoter.

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