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Lei Wang, Jingang Li, Lei Li and Sixun Zheng Organic–inorganic hybrid diblock copolymer composed of poly (ε-caprolactone) and poly(MA POSS): Synthesis and its nanocomposites with epoxy resin Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 14 FEB 2013 | DOI: 10.1002/pola.26597

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The synthesis of organic-inorganic hybrid diblock copolymers composed of poly(ε-caprolactone) and poly(MA POSS) [PCL-b-P(MA POSS)] via reversible addition-fragmentation chain transfer polymerization of 3-methacryloxypropylheptaphenyl polyhedral oligomeric silsesquioxane with dithiobenzoate-terminated poly(ε-caprolactone) as the macromolecular chain transfer agent is reported. The organic–inorganic diblock copolymer was incorporated into epoxy and the organic–inorganic nanocomposites were successfully obtained.

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