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Yasuhiro Morisaki, Masayuki Gon and Yoshiki Chujo Conjugated microporous polymers consisting of tetrasubstituted [2.2]Paracyclophane junctions Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 22 FEB 2013 | DOI: 10.1002/pola.26600

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Conjugated microporous polymers (CMPs) were synthesized from the tetrasubstituted [2.2]paracyclophane skeleton as a tetra-functional building block using Hay coupling, Sonogashira–Hagihara cross-coupling, and Yamamoto coupling. The CMPs exhibited microporosity (less than 2 nm) and large surface areas (up to approximately 1000 m2 g–1). The CMPs consisted of relatively uniform particles and dispersed in organic solvents.

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