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Jicheol Park, Hong Chul Moon and Jin Kon Kim Facile synthesis for well-defined A2B miktoarm star copolymer of poly(3-hexylthiophene) and poly(methyl methacrylate) by the combination of anionic polymerization and click reaction Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 14 FEB 2013 | DOI: 10.1002/pola.26604

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This article reports the facile synthesis of Miktoarm star copolymer composed of P3HT and PMMA ((P3HT)2PMMA). The optical property and thin-film morphology of (P3HT)2PMMA were investigated. Two linear P3HT-b-PMMAs are also synthesized to compare fibril structure of P3HT blocks. The π–π interaction between P3HT arms in (P3HT)2PMMA was strong enough to arrange two P3HT backbone chains in (P3HT)2PMMA to stack one by one along the nanofibril axis.

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