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Dorota Neugebauer, Anna Mielańczyk, Sylwia Waśkiewicz and Tadeusz Biela Epoxy functionalized polymethacrylates based on various multifunctional d-glucopyranoside acetals Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 13 MAR 2013 | DOI: 10.1002/pola.26642

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The bromoester functionalized d-glucopyranoside acetals based on methyl α-d-glucopyranoside (MeαdGlu) or 2-(hydroxymethyl)phenyl-β-d-glucopyranoside (salicin) are prepared and used to initiate the controlled atom transfer radical copolymerization of glycidyl and methyl methacrylates in the presence of CuCl/dNbpy in anisole at 30 °C. The well-defined copolymers with sugar cores sheltered by two-, three-, four-, or six-polymethacrylate segments with various polymerization degrees (DParm = 15–70) and low dispersity indices (Ð = 1.15–1.30) are successfully synthesized.

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