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Da-Wei Wan, Zhou Chen, Yan-Shan Gao, Qi Shen, Xiu-Li Sun and Yong Tang Synthesis and characterization of tridentate [O−N(H)X] titanium complexes and their applications in olefin polymerization Journal of Polymer Science Part A: Polymer Chemistry 51

Version of Record online: 13 MAR 2013 | DOI: 10.1002/pola.26643

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The (arylamino)methylene phenolate titanium (IV) complexes are thermally stable and active to promote ethylene polymerization and copolymerization with 1-alkenes at a high temperature (up to 150 °C). 1-Octene and 1-octadencene are suitable comonomers. The highest activity is 1.89 × 106 g/mol·Ti·h·atm. The introduction of the pendant PPh2 group is important to the catalytic behaviors of the complexes.

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