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Itaru Natori, Shizue Natori, Anna Kanasashi, Kosuke Tsuchiya and Kenji Ogino Formation of a porphyrin/fullerene light-harvesting system from self-assembly of porphyrin-end-functionalized polycyclohexane and [6,6]-phenyl-C61-butyric acid methyl ester: Effects of microphase separation and π–π interactions Journal of Polymer Science Part B: Polymer Physics 51

Article first published online: 27 NOV 2012 | DOI: 10.1002/polb.23222

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Thin films composed of zinc tetraphenylporphyrin-end-functionalized polycyclohexane and [6,6]-phenyl-C61-butyric acid methyl ester blends are prepared to investigate their potential as light-harvesting systems within PSCs. The extent to which the absorption bands of the films overlapped the terrestrial solar spectrum is increased considerably when the blends formed a co-continuous structure. These polymer blend films may be considered as viable candidates for light-harvesting systems within PSCs.

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