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Daniel A. Kaplowitz, Guoqiang Jian, Karen Gaskell, Aldo Ponce, Panju Shang and Michael R. Zachariah Aerosol Synthesis and Reactivity of Thin Oxide Shell Aluminum Nanoparticles via Fluorocarboxylic Acid Functional Coating Particle & Particle Systems Characterization 30

Version of Record online: 7 AUG 2013 | DOI: 10.1002/ppsc.201300112

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An aerosol phase passivation coating of perfluoropentanoic acid on in situ generated bare nanoaluminum is accomplished, demonstrating a bridge bonding coordination between carboxylate and aluminum, a 1–2 nm coating layer, and enhanced active aluminum fuel content. The product exhibits a reduced ignition temperature in thermite combination with copper oxide.

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