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Yufeng Liu, Meiying Ge, Yang Yue, Yan Sun, Yizheng Wu, Xin Chen and Ning Dai Colloidal Cu2ZnSnS4 nanocrystals generated by a facile route using ethylxanthate molecular precursors physica status solidi (RRL) - Rapid Research Letters 5

Article first published online: 3 FEB 2011 | DOI: 10.1002/pssr.201004528

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This Letter reports on the use of zinc ethylxanthate (Zn(ex)2) and copper ethylxanthate (Cu(ex)2) for preparing quaternary Cu2ZnSnS4 (CZTS) colloidal nanocrystals. As air-stable molecular precursors, Zn(ex)2 and Cu(ex)2 can optimize the synthesis of quaternary CZTS nanocrystals because Cu(ex)2) and Zn(ex)2 support the formation of homogeneous precursor solutions including all precursors, and thus the flexible production of CZTS nanocrystals in homogeneous reaction solutions.

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