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Bongjin Simon Mun, Kai Chen, Youngchul Leem, Catherine Dejoie, Nobumichi Tamura, Martin Kunz, Zhi Liu, Michael E. Grass, Changwoo Park, Joonseok Yoon, Y. Yvette Lee and Honglyoul Ju Observation of insulating–insulating monoclinic structural transition in macro-sized VO2 single crystals physica status solidi (RRL) - Rapid Research Letters 5

Article first published online: 21 JAN 2011 | DOI: 10.1002/pssr.201105011

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This Letter reports first observation of M1, M2, and R phases in VO2 single crystals exhibiting two transitions: an insulator–insulator transition (IIT) at ∼49 °C and the well-known first-order metal–insulator transition (MIT) at 67.8 °C with transition width ∼0.01 °C. We believe that further investigations on this intriguing system will not only enrich the fundamental understanding of the system, but will also be exploited in future technologies.

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