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Mitsutaka Okumura, Yasuyuki Nakanishi, Keiji Kinoshita, Satoru Yamada, Yasutaka Kitagawa, Takashi Kawakami, Shunsuke Yamanaka, Toru Amaya and Toshikazu Hirao Theoretical investigation for the stability of the concave-bound cyclopentadienyl iron complex of sumanene International Journal of Quantum Chemistry 113

Article first published online: 19 MAR 2012 | DOI: 10.1002/qua.24057

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When metals interact with curved carbon π-surfaces they show a clear preference to binding to the convex side rather than the concave one. However, stereoselectivity of iron complexes for the concave surface of sumanene can be achieved with the selection of appropriate counterions.

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