E-mail

E-mail a Wiley Online Library Link

Alexey V. Salin, Roza M. Aminova and Vladimir I. Galkin Quantum chemical investigation on the reaction mechanism of tertiary phosphines with unsaturated carboxylic acids: An insight into kinetic data International Journal of Quantum Chemistry 113

Article first published online: 22 MAY 2012 | DOI: 10.1002/qua.24161

Thumbnail image of graphical abstract

Recent computational and experimental studies revealed the paramount importance of proton-transfer processes in phosphine- and amine-catalyzed reactions of unsaturated electrophilic reagents: they can be rate-determining steps and/or require involvement of external proton-donor sources. A similar mechanism was found for quarternization of tertiary phosphines with unsaturated carboxylic acids.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

Choose captcha format: Image or Audio. Click here if you need help.

SEARCH