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Alexey V. Salin, Roza M. Aminova and Vladimir I. Galkin Quantum chemical investigation on the reaction mechanism of tertiary phosphines with unsaturated carboxylic acids: An insight into kinetic data International Journal of Quantum Chemistry 113

Article first published online: 22 MAY 2012 | DOI: 10.1002/qua.24161

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Recent computational and experimental studies revealed the paramount importance of proton-transfer processes in phosphine- and amine-catalyzed reactions of unsaturated electrophilic reagents: they can be rate-determining steps and/or require involvement of external proton-donor sources. A similar mechanism was found for quarternization of tertiary phosphines with unsaturated carboxylic acids.

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