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Boris F. Minaev, N. Arul Murugan and Hans Ågren Dioxygen spectra and bioactivation International Journal of Quantum Chemistry 113

Article first published online: 25 JAN 2013 | DOI: 10.1002/qua.24390

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The excited states of dioxygen are involved in both oxidative organic photochemistry, including photosynthesis, and dark enzymatic reactions. The key mechanisms of spin-states mixing induced by spin-orbit coupling in molecular O2 and possible ways to overcome spin prohibition for various photophysical and biochemical processes involving dioxygen are discussed in this review.

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